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Efficient and self-healing copper halide Cs3Cu2Cl5 film assisted by microwave treatment for high-resolution X-ray imaging

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机构: [1]Kunming Univ Sci & Technol, Coll Mat Sci & Engn, Key Lab Adv Mat Yunnan Prov, Kunming 650093, Peoples R China [2]Chongqing Univ Arts & Sci, Res Inst New Mat Technol, Chongqing 402160, Peoples R China [3]Kunming Univ Sci & Technol, Affiliated Hosp, Peoples Hosp Yunnan Prov 1, Kunming 650031, Peoples R China [4]Natl Res Nucl Univ, Inst Nanoengn Elect Spintron & Photon, MEPhI Moscow Engn Phys Inst, Moscow 115409, Russia
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关键词: Lead-free metal halide Cs3Cu2Cl5 ??????? X-ray imaging Microwave Self-healing

摘要:
Lead-free Cs3Cu2Cl5 metal halide exhibits high photoluminescence quantum yield (PLQY), large Stokes shifts and small self-absorption due to self-trapped excitons (STE) emission, which undoubtedly is a potential scintillator material. However, Cs3Cu2Cl5 nanocrystals (NCs) are susceptible to degradation by moisture at high humidity environment, which severely affects its long-term application in X-ray imaging. Herein, we prepared Cs3Cu2Cl5 scintillator films with a PLQY of 72.4% and a high spatial resolution of 20 lp mm(-1). Moreover, we firstly propose a self-healing strategy with facile microwave treatment to recover the crystal structure of Cs3Cu2Cl5 film which damaged by moisture, while the photoluminescence (PL) and radioluminescence (RL) intensities of the damaged Cs3Cu2Cl5 film are repaired to more than 95% and the spatial resolution can be restored to 20 lp mm(-1). Furtherly, the imaging quality of the self-healing scintillator film can be maintained stably by cyclic microwave treatment. It found that microwave treatment provides a simultaneous and molecular level heating environment for the Cs3Cu2Cl5 film, which drives the hydrolysates to re-crystallize along with the surface of the destroyed crystals. Therefore, microwave treatment opens a new avenue to recover Cs3Cu2Cl5 films degraded by moisture, and provides a solution for long-term application of scintillator films at low cost.

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出版当年[2022]版:
大类 | 1 区 材料科学
小类 | 1 区 材料科学:硅酸盐
最新[2025]版:
大类 | 2 区 材料科学
小类 | 2 区 材料科学:硅酸盐
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出版当年[2021]版:
Q1 MATERIALS SCIENCE, CERAMICS
最新[2023]版:
Q1 MATERIALS SCIENCE, CERAMICS

影响因子: 最新[2023版] 最新五年平均 出版当年[2021版] 出版当年五年平均 出版前一年[2020版] 出版后一年[2022版]

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第一作者机构: [1]Kunming Univ Sci & Technol, Coll Mat Sci & Engn, Key Lab Adv Mat Yunnan Prov, Kunming 650093, Peoples R China [2]Chongqing Univ Arts & Sci, Res Inst New Mat Technol, Chongqing 402160, Peoples R China
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通讯机构: [1]Kunming Univ Sci & Technol, Coll Mat Sci & Engn, Key Lab Adv Mat Yunnan Prov, Kunming 650093, Peoples R China [2]Chongqing Univ Arts & Sci, Res Inst New Mat Technol, Chongqing 402160, Peoples R China [*1]College of Materials Science and Engineering, Key Laboratory of Advanced Materials of Yunnan Province, Kunming University of Science and Technology, Kunming, 650093, PR China.
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