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Environmentally benign cinchonain IIa from Uncaria laevigata for corrosion inhibition of Q235 steel in HCl corrosive medium: Experimental and theoretical investigation

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机构: [1]Weihai Key Laboratory of Active Factor of Marine Products, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150006, PR China [2]The Second People’s Hospital of Baoshan City,Yunnan Province, Baoshan, 678000, PR China [3]The New NO.1 High School of Wendeng District, Weihai, 264400, PR China
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关键词: Cinchonain IIa Uncaria laevigata Green corrosion inhibitor Molecular dynamics DFT-Modeling

摘要:
Traditional corrosion inhibitors make great contribution to metal protection, but also cause environmental pollution. To solve the problem, plant extracts as green corrosion inhibitors have attracted much attention in recent years. Plants are good raw materials for corrosion inhibitors and also meet the requirements of industry. However, they have not been successfully applied in industry due to the unknown composition of the effective corrosion inhibitors and large dosage thereof. Therefore, cinchonain IIa was separated from Uncaria laevigata with abundant sources and low cost from nature in this work. Here we hypothesized that cinchonain IIa could show good corrosion inhibition performance for Q235 steel in the acidic medium. Through experiments and theoretical calculation, we studied the corrosion inhibition effect of cinchonain IIa on Q235 in 1 M HCl solution at 298 K for 48 h. Electrochemical experiments revealed that the inhibition efficiency of 200 mg/L cinchonain IIa in 1 M HCl for Q235 steel was 94.08% for 48 h. It even showed over 93% corrosion inhibition efficiency and durable protection performance to 28 d. Surface observations indicated that cinchonain IIa were firmly attached to the steel surface by forming a protective film. Moreover, quantum chemical calculation and molecular dynamics simulation revealed the inhibition mechanism at molecular and atomic level. Compared with some plant extracts, here we demonstrate that the outstanding advantages of cinchonain IIa include sustained protective effect, small dosage, and low toxicity. Accordingly, it may be used as a green industrial corrosion inhibitor with great potential in oilfield acidification and acid pickling.Copyright © 2022 Elsevier Inc. All rights reserved.

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出版当年[2022]版:
大类 | 2 区 环境科学与生态学
小类 | 2 区 公共卫生、环境卫生与职业卫生 2 区 环境科学
最新[2023]版:
大类 | 2 区 环境科学与生态学
小类 | 1 区 公共卫生、环境卫生与职业卫生 2 区 环境科学
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第一作者机构: [1]Weihai Key Laboratory of Active Factor of Marine Products, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150006, PR China
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