Phytochemical investigation on the aerial parts of Melodinus hemsleyanus diels (Jahrb, Syst, 1995) led to the isolation and identification of 27 compounds, including fifteen aspidosperma-type alkaloids (1-15), four quinoline-type alkaloids (16-19), three quebrachamine-type alkaloids (20-22), and five eburna-type alkaloids (23-27). The structure of compound 1 was elucidated by means of spectroscopic analysis, including HRESIMS, and 1D and 2D NMR experiments. Compounds 1-2, 6, 10, 12, 13, 15, 16 and 20-27 are herein reported for the first time from the studied plant, while the compounds 1-2 and 21 have not previously been recorded in the genus Melodinus. The aspidosperma-type monoterpenoid indole alkaloids in M. hemsleyanus could serve as chemotaxonomic markers.
基金:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China [31600274]; Applied Basic Research Project of Yunnan Province [2018FB036]
第一作者机构:[1]Kunming Univ Sci & Technol, Yunnan Inst Food Safety, Kunming 650500, Yunnan, Peoples R China
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推荐引用方式(GB/T 7714):
Wang Jin-Tang,Liang Li-Wen,Li Fang-Ru,et al.Chemical constituents of Melodinus hemsleyanus diels[J].BIOCHEMICAL SYSTEMATICS AND ECOLOGY.2019,84:71-74.doi:10.1016/j.bse.2019.04.007.
APA:
Wang, Jin-Tang,Liang, Li-Wen,Li, Fang-Ru,Khan, Afsar,Liu, Lu...&Zhao, Tian-Rui.(2019).Chemical constituents of Melodinus hemsleyanus diels.BIOCHEMICAL SYSTEMATICS AND ECOLOGY,84,
MLA:
Wang, Jin-Tang,et al."Chemical constituents of Melodinus hemsleyanus diels".BIOCHEMICAL SYSTEMATICS AND ECOLOGY 84.(2019):71-74