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Chemical constituents of Melodinus hemsleyanus diels

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机构: [1]Kunming Univ Sci & Technol, Yunnan Inst Food Safety, Kunming 650500, Yunnan, Peoples R China [2]Kunming Univ Sci & Technol, Peoples Hosp Yunnan Prov 1, Affiliated Hosp, Kunming 650032, Yunnan, Peoples R China [3]COMSATS Univ Islamabad, Dept Chem, Abbottabad Campus, Abbottabad 22060, Pakistan [4]Yunnan Univ Chinese Med, Yunnan Key Lab Dai & Yi Med, Kunming 650000, Yunnan, Peoples R China
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关键词: Melodious hemsleyanus Apocynaceae Alkaloids Chemotaxonomy

摘要:
Phytochemical investigation on the aerial parts of Melodinus hemsleyanus diels (Jahrb, Syst, 1995) led to the isolation and identification of 27 compounds, including fifteen aspidosperma-type alkaloids (1-15), four quinoline-type alkaloids (16-19), three quebrachamine-type alkaloids (20-22), and five eburna-type alkaloids (23-27). The structure of compound 1 was elucidated by means of spectroscopic analysis, including HRESIMS, and 1D and 2D NMR experiments. Compounds 1-2, 6, 10, 12, 13, 15, 16 and 20-27 are herein reported for the first time from the studied plant, while the compounds 1-2 and 21 have not previously been recorded in the genus Melodinus. The aspidosperma-type monoterpenoid indole alkaloids in M. hemsleyanus could serve as chemotaxonomic markers.

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出版当年[2019]版:
大类 | 4 区 生物
小类 | 4 区 生化与分子生物学 4 区 生态学 4 区 进化生物学
最新[2023]版:
大类 | 4 区 生物学
小类 | 4 区 生化与分子生物学 4 区 生态学 4 区 进化生物学
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出版当年[2018]版:
Q4 EVOLUTIONARY BIOLOGY Q4 ECOLOGY Q4 BIOCHEMISTRY & MOLECULAR BIOLOGY
最新[2023]版:
Q3 ECOLOGY Q4 BIOCHEMISTRY & MOLECULAR BIOLOGY Q4 EVOLUTIONARY BIOLOGY

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第一作者机构: [1]Kunming Univ Sci & Technol, Yunnan Inst Food Safety, Kunming 650500, Yunnan, Peoples R China
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